Suppose that S(u) and S(v) are not disjoint. Choose a vertex w in S(u) ∩ S(v).

Since wS(u), for every vertex xS(u), there is a directed path from w to x and from x to w. Similarly, since wS(v), for every vertex yS(v), there is a directed path from w to y and from y to w.

Putting those paths together, there is a directed path from x to y and from y to x (going through w) for all xS(u) and yS(v). That means x and y are in the same strongly connected component.

Since x is an arbitrary member of S(u) and y is an arbitrary member of S(v), S(u) must be the same as S(v).